On 24 June 2016, Stoessel released her first solo single, "Great Escape", along with the Spanish-language version of the song, "Yo Me Escaparé".
The music video for "Great Escape" was filmed in Buenos Aires and later released on 8 July 2016.
The song was later released on an album for the series in March 2012.
Stoessel's father presented an unrelated project to Disney Channel producers, who later informed him about auditions for the lead role for the network's upcoming television series, Violetta.
The showcase was filmed and broadcast on her official You Tube channel from 22 August until 28 August 2016.
In June, Stoessel was featured on "Todo Es Posible", a collaboration with Spanish singer David Bisbal for the Tad Jones: The Hero Returns movie soundtrack.
and she also appeared alongside fellow artist and the Voz Por La Paz foundation patron Odino Faccia on the world peace anthem, "Somos El Cambio", which was written by the former President of the United States, Barack Obama, and the song was first performed at the Red Voz Por La Paz ceremony the previous year.
The same month, Stoessel held a free musical concert near the Monument to the Carta Magna and Four Regions of Argentina, organized by the city government of Buenos Aires, under the slogan "Cuidemos el planeta".
In September 2014, Stoessel performed at the charity soccer match Partido Interreligioso por la Paz, convened by Pope Francis at the Stadio Olimpico in Rome where she sang "Nel Mio Mondo" and the cover version of John Lennon's song "Imagine".